Creosote
The deposit annual sweeping exists to remove — and how fast it builds is mostly down to your firewood.
Residue left when wood smoke cools and condenses on the flue wall. How quickly it accumulates depends far more on fuel moisture and how hot you burn than on anything about the chimney, which is why two identical houses can need very different sweep intervals. Left to harden it stops brushing out, and removal gets considerably more expensive.
